Title
A sulfur self-doped multifunctional biochar catalyst for overall water splitting and a supercapacitor from Camellia japonica flowers
Author
Chengkai Xia, Subramani Surendran, Seulgi Ji, Dohun Kim, Yujin Chae, Jaekyum Kim, Minyeong Je, Mi-Kyung Han, Woo-Seok Choe, Chang Hyuck Choi, Heechae Choi, Jung Kyu Kim, Uk Sim
Year
2022
Journal
CARBON ENERGY
Abstract
A versatile use of a sulfur self-doped biochar derived from Camellia japonica (camellia) flowers is demonstrated as a multifunctional catalyst for overall water splitting and a supercapacitor. The native sulfur content in the camellia flower facilitates in situ self-doping of sulfur, which highly activates the camellia-driven biochar (SA-Came) as a multifunctional catalyst with the enhanced electron-transfer ability and long-term durability. For water splitting, an SA-Came-based electrode is highly stable and shows reaction activities in both hydrogen and oxygen evolution reactions, with overpotentials of 154 and 362 mV at 10 mA cm−2, respectively. For supercapacitors, SA-Came achieves a specific capacitance of 125.42 F g−1 at 2 A g−1 and high cyclic stability in a three-electrode system in a 1 M KOH electrolyte. It demonstrated a high energy density of 34.54 Wh kg−1 at a power density of 1600 W kg−1 as a symmetric hybrid supercapacitor device with a wide working potential range of 0–1.6 V.
Full Article
Instrument
NRS-5100
Keywords
catalyst, symmetric hybrid supercapacitor