Absolute configuration of resveratrol oligomer glucosides isolated from the leaves of Upuna borneensis

July 28, 2017

Title

Absolute configuration of resveratrol oligomer glucosides isolated from the leaves of Upuna borneensis

Author

Tetsuro Ito, Hiromi Ito, Munekazu Iinuma

Year

2017

Journal

Phytochemistry Letters

Abstract

A comprehensive investigation of the chemical constituents of the leaves of Upuna borneensis (Dipterocarpaceae) was performed. Three new glucosides of resveratrol oligomers having a pentameric aglycone [upunoside E (1)] and dimeric aglycones [upunosides F (3) and G (4)], as well as 14 resveratrol derivatives (2, 5–17), were isolated. The absolute configurations of the new compounds were elucidated by spectroscopic analysis, including two-dimensional NMR and CD spectra.

Instrument

J-820

Keywords

Circular dichroism, Absolute configuration, Pharmaceutical