Circularly Polarized Blue Luminescent Spherulites Consisting of Hierarchically Assembled Ionic Conjugated Polymers with a Helically π‐Stacked Structure
Cationic π‐conjugated polymers form an interchain helically π‐stacked assembly with anionic chiral compounds that is stabilized by both electrostatic and π−π interactions to hierarchically self‐organize into a spherulite with a circularly polarized blue luminescence. To the best of our knowledge, this is the first example of a chiroptical spherulite that is hierarchically constructed from π‐conjugated polymers.
V-570, FP-750, J-820, CPL-200
Absorption, Circular dichroism, Stereochemistry, Chemical stability, Thermal stability, Polymers, Fluorescence, Photoluminescence, Quantum yield, Circularly polarized luminescence, Materials