Circularly Polarized Blue Luminescent Spherulites Consisting of Hierarchically Assembled Ionic Conjugated Polymers with a Helically π-Stacked Structure

September 9, 2021

Title

Circularly Polarized Blue Luminescent Spherulites Consisting of Hierarchically Assembled Ionic Conjugated Polymers with a Helically π-Stacked Structure

Author

Kazuyoshi Watanabe, Hiroshi Iida, Kazuo Akagi

Year

2012

Journal

Advanced Materials Volume24, Issue48 December 18, 2012 Pages 6451-6456

Abstract

Cationic π-conjugated polymers form an interchain helically π-stacked assembly with anionic chiral compounds that is stabilized by both electrostatic and π−π interactions to hierarchically self-organize into a spherulite with a circularly polarized blue luminescence. To the best of our knowledge, this is the first example of a chiroptical spherulite that is hierarchically constructed from π-conjugated polymers.

Instrument

CPL-300

Keywords

Circularly Polarized Luminescence