Title
Cis-Bis(2,2′-Azopyridinido)dicarbonylruthenium(II)
Author
Tsugiko Takase
Year
2021
Journal
molbank
Abstract
An [Ru(apy)2Cl2] precursor (apy = 2,2′-azopyridine) in 2-methoxyethanol was heated under a pressurized CO atmosphere to afford a diradical complex, [Ru(apy·−)2(CO)2], containing one-electron-reduced azo anion radical ligands. The electronic states of the complex were characterized by spectroscopic techniques and computational studies. Magnetic measurements revealed the existence of antiferromagnetic interactions in the diradical complex.
Full Article
Instrument
FT/IR-4100,V-560
Keywords
ruthenium, carbonyl complex, azopyridine,magnetic properties