Heterodinuclear Group 13 Element Complexes of N4O6‐Type Dipyrrin with an Unsymmetrical Twisted Structure

April 9, 2019

Title

Heterodinuclear Group 13 Element Complexes of N4O6‐Type Dipyrrin with an Unsymmetrical Twisted Structure

Author

Makoto Saikawa, Takumu Noda, Ryota Matsuoka, Takashi Nakamura, Tatsuya Nabeshima

Year

2018

Journal

European Journal of Inorganic Chemistry

Abstract

Heterodinuclear group 13 element complexes of an N4O6‐type dipyrrin cyclic dimer were synthesized by the stepwise reaction with boron and group 13 elements (Al, Ga, and In). The macrocycles have a new type of unsymmetrical twisted (pseudo‐figure‐of‐eight) structure.

Instrument

V-670, FP-8600

Keywords

Optical properties, Inorganic chemistry, Fluorescence