Strong circularly polarized luminescence induced from chiral supramolecular assembly of helical nanorods

June 29, 2020

Title

Strong circularly polarized luminescence induced from chiral supramolecular assembly of helical nanorods

Year

2017

Journal

Chemical Communications

Abstract

Chiral supramolecular assemblies (BNS–BPP) can be self-assembled by electrostatic and π–π stacking interactions between the chiral binaphthyl sulphonate (BNS) anion and the achiral bipyrene-based pyridinium (BPP) cation chromophore. BNS–BPP can exhibit strong CD and circularly polarized luminescence (CPL) signals, and the dissymmetry factor glum values can be up to 0.079.

Instrument

CPL-300, J-810

Keywords

Circular dichroism, Circularly polarized luminescence, Stereochemistry, Nanostructures, Materials