Synthesis and application of reversible fluorescent photochromic molecules based on tetraphenylethylene and photochromic groups

April 9, 2019

Title

Synthesis and application of reversible fluorescent photochromic molecules based on tetraphenylethylene and photochromic groups

Author

Shanchao Peng, Jiahui Wen, Mingtan Hai, Zhou Yang, Xiaotao Yuan, Dong Wang, Hui Cao, Wanli He

Year

2018

Journal

New Journal of Chemistry

Abstract

Tetraphenylethylene-naphthopyran (TPE-NP) and tetraphenylethylene-spirooxazine (TPE-SO) with conjugated photochromic groups and fluorophores were designed and synthesized. Both of them exhibit the comprehensive effects of aggregation-induced emission (AIE) and photochromism while different photochromic groups lead to a unique photochromic rate and fluorescence intensity. Among them, TPE-NP has significant photochromic and fluorescence effects with good stability. Therefore, it could be used as an anti-counterfeiting ink and is expected to be used in fluorescence switches in the future.

Instrument

V-570

Keywords

Kinetics, Photo stability, Materials