Synthesis and properties of chiral nanoparticles based on (pS)- and (pR)-decasubstituted pillararenes containing secondary amide fragments
D. N. Shurpik, P. L. Padnya, V. G. Evtugyn, T. A. Mukhametzyanov, A. A. Khannanov, M. P. Kutyreva, I. I. Stoikov
Employing induced asymmetric synthesis, new decasubstituted pillararenes containing (R)-(+)- or (S)-(−)-1-phenylethane-1-acetamide fragments have been obtained and characterized. Using NTA and TEM, and circular dichroism spectroscopy, it was shown that the amidopillararenes synthesized form spherical chiral nanoscale aggregates in CHCl3. During heating, both positive and negative Cotton effects corresponding to nanoparticles in CHCl3reversibly decrease. Keeping the nanoparticles at room temperature results in a decrease in their size and intensification of the Cotton effect.
Circular dichroism, Stereochemistry, Thermal stability, Thermodynamics, Chemical stability, Aggregation, Nanostructures, Materials