Title
Synthesis, characterization and structural study of new vanadium complexes with phenolic oxime ligands
Author
Ilyas Belkhettab, Sultana Boutamine, Hennia Slaouti, Mohamed Faouzi Zid, Habib Boughzala, Zakia Hank
Year
2020
Journal
Journal of Molecular Structure
Abstract
In this work, three new vanadium complexes are reported. Their synthesis, crystallization and characterization are detailed. The complex (1) [VO(C7H6NO2)2] is a mononuclear and crystallizes in the monoclinic P21/n space group exhibiting a square pyramidal geometry around the vanadium. Dissolved in p-xylene (1–4 dimethylbenzene), this complex gives a binuclear complex (2) [V2O2(C7H6NO2)2(C7H5NO2)2]·C8H10 with a triclinic P-1 space group and an octahedral geometry around the vanadium. The complex (3) [VO2(C9H9N2O3)] was obtained using the new iminoacylated oxime ligand (the result of the nucleophilic attack of 4-hydroxysalicylaldoxime with acetonitrile), it crystallizes in the triclinic P-1 space group with a trigonal bipyramidal geometry around the vanadium. All complexes were characterized by single crystal X-ray diffraction, FT-IR, NMR, UV–visible and TGA.
Instrument
V-650
Keywords
Absorption, Coordination chemistry, Inorganic chemistry