A novel flow injection chemiluminescence determination of Cr(VI) with Dichlorotris(1,10-phenanthroline)ruthenium(II)

By M.D. Luaces, N.C. Martínez, M. Granda, A.C. Valdés, C. Pérez-Conde, A.M. Gutiérrez

April 23, 2020

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Title

A novel flow injection chemiluminescence determination of Cr(VI) with Dichlorotris(1,10-phenanthroline)ruthenium(II)

Author

M.D. Luaces, N.C. Martínez, M. Granda, A.C. Valdés, C. Pérez-Conde, A.M. Gutiérrez

Year

2011

Journal

Talanta

Abstract

A selective novel reverse flow injection system with chemiluminescence detection (rFI-CL) for the determination of Cr(VI) in presence of Cr(III) with Dichlorotris (1,10-phenanthroline)ruthenium(II), (Ru(phen)3Cl2), is described in this work. This new method is based on the oxidation capacity of Cr(VI) in H2SO4 media. First, the Ruthenium(II) complex is oxidized to Ruthenium(III) complex by Cr(VI) and afterwards it is reduced to the excited state of the Ruthenium(II) complex by a sodium oxalate solution, emitting light inside the detector. The intensity of chemiluminescence (CL) is proportional to the concentration of Cr(VI) and, under optimum conditions, it can be determined over the range of 3–300 g L−1 with a detection limit of 0.9 g L−1. The RSD was 8.4% and 1.5% at 5 and 50 g L−1, respectively. For the rFI-CL method various analytical parameters were optimized: flow rate (1 mL min−1), H2SO4 carrier concentration (20% w/V), Ru(phen)3Cl2 concentration (5 mM) and sodium oxalate concentration (0.1 M). The effect of Cr(III), Fe(III), Al(III), Cd(II), Zn(II), Hg(II), Pb(II), Ca(II) and Mg(II), was studied. The method is highly sensitive and selective, allowing a fast, on-line determination of Cr(VI) in the presence of Cr(III). Finally, the method was tested in four different water samples (tap, reservoir, well and mineral), with good recovery percentage.

Full Article

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Instrument

HPLC

Keywords

HPLC, Chemiluminescence, Cr(VI), Dichlorotris(1,10-phenanthroline)ruthenium(II), Flow injection