Title
Composite Cholesteric Nanocellulose Films with Enhanced Mechanical Properties
Author
Brandon Vollick, Pei-Yu Kuo, Héloïse Thérien-Aubin, Ning Yan, Eugenia Kumacheva
Year
2016
Journal
Chemistry of Materials
Abstract
Cellulose nanocrystals (CNCs) form cholesteric films that exhibit birefringence, iridescence, and circular dichroism, however these films are brittle and prone to cracking. Here we report composite cholesteric films formed from CNCs and soft reactive latex NPs (the latter underwent in-situ crosslinking during film formation). Composite films exhibited a self-stratified mor-phology, with lateral cholesteric CNC-rich layers and isotropic latex NP-rich layers. The films retained their photonic properties and exhibited significantly enhanced mechanical properties. In comparison with latex-free CNC films, composite films had 60 % higher toughness but did not compromise their tensile strength. The combination of photonic performance and improved mechanical properties of the composite nanocellulose films expands the range of applications of these materials for the fabrication of optical devices.
Instrument
J-810
Keywords
Circular dichroism, Stereochemistry, Materials