Designing of an artificial light energy converter in the form of short-chain dyad when combined with core-shell gold/silver nanocomposites

May 22, 2018

Title

Designing of an artificial light energy converter in the form of short-chain dyad when combined with core-shell gold/silver nanocomposites

Author

Gopa Dutta (Pal), Somnath Paul, Munmun Bardhan, Asish De, Tapan Ganguly

Year

2017

Journal

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy

Abstract

UV–vis absorption, steady state and time resolved fluorescence and absorption spectroscopic investigations demonstrate that the short chain dyad MNTMA when combined with gold-silver core-shell (Au@Ag) nanocomposite , forms elongated conformers in the excited state whereas for the dyad – Ag (spherical) system the majority of dyads remains in a folded conformation. In the dyad-core-shell nanocomposite system, energy wasting charge recombination rate slows down primarily due to elongated conformation and thus it may be anticipated that this hybrid nanocomposite system may serve as a better light energy conversion device.

Instrument

FP-8200

Keywords

Fluorescence, Nanostructures, Inorganic chemistry, Materials