Title
Circularly Polarized Luminescence of a Fluorescent Chiral Binaphtylene–Perylenebiscarboxydiimide Dimer
Author
Tsuyoshi Kawai, Kensuke Kawamura, Hiroyuki Tsumatori, Masaaki Ishikawa, Masanobu Naito, Michiya Fujiki, Takuya Nakashima
Year
2007
Journal
ChemPhysChem
Abstract
he chiral perylene dimer shows strong fluorescence with quantum efficiency as high as 88 % and with significantly large circularly polarized dissymmetry, gCPL=3×10−3. Its promising chiroptical properties, originating from the efficient intramolecular exciton coupling between the fluorescent groups, make it suitable for use as a standard reference.
Instrument
J-725
Keywords
Circular dichroism, Chemical stability, Stereochemistry, Organic chemistry, Materials