Title
Vibrational Optical Activity of BODIPY Dimers: The Role of Magnetic–Electric Coupling in Vibrational Excitons
Author
Sergio Abbate, Torsten Bruhn, Gennaro Pescitelli, Giovanna Longhi
Year
2017
Journal
The Journal of Physical Chemistry A
Abstract
The vibrational exciton (VE) interpretation of intense bisignated couplets in vibrational circular dichroism (VCD) spectra of a pair of atropisomeric BODIPY (boron dipyrrin) dimers is discussed. The role of intrinsic magnetic moments is crucial to reproduce the different behaviors of quasi-isomeric BODIPY dimers with different aryl junction.
Instrument
FVS-6000
Keywords
Vibrational circular dichroism, Magnetic–Electric Coupling, Vibrational Excitons