Title
A Thermostable Three-Dimensional Homochiral Metal–Organic Framework Constructed from N-Rich Ligand: Syntheses, Crystal Structures, and Properties
Author
Hao Qian, Chuming He, Shihan Pan, Shuyu Tang, Yijie Liu, Shengjun Deng, Weiming Xiao, Ning Zhang
Year
2019
Journal
Journal of Inorganic and Organometallic Polymers and Materials
Abstract
By using the designed N-rich 3,6-bis(4-methyl-1H-imidazol-1-yl)pyridazine (b4mmp) and chiral d-camphoric acid (d-cam) ligands to react with cadmium acetate, a new bulk homochiral 3D metal–organic framework [Cd2(d-cam)2(b4mmp)(DMF)]n (1) has been synthesized. Compound 1 bears an uninodal 6-connected net structure with unprecedent topology, and it has a high thermostability. Moreover, the circular dichroism spectrum and photoluminescent properties for 1 were also investigated.
Instrument
J-1500
Keywords
Circular dichroism, Solid state, Stereochemistry, Organic chemistry