A Thermostable Three-Dimensional Homochiral Metal–Organic Framework Constructed from N-Rich Ligand: Syntheses, Crystal Structures, and Properties

By Hao Qian, Chuming He, Shihan Pan, Shuyu Tang, Yijie Liu, Shengjun Deng, Weiming Xiao, Ning Zhang

March 24, 2020

  • Year

  • Technique

  • Industry

Title

A Thermostable Three-Dimensional Homochiral Metal–Organic Framework Constructed from N-Rich Ligand: Syntheses, Crystal Structures, and Properties

Author

Hao Qian, Chuming He, Shihan Pan, Shuyu Tang, Yijie Liu, Shengjun Deng, Weiming Xiao, Ning Zhang

Year

2019

Journal

Journal of Inorganic and Organometallic Polymers and Materials

Abstract

By using the designed N-rich 3,6-bis(4-methyl-1H-imidazol-1-yl)pyridazine (b4mmp) and chiral d-camphoric acid (d-cam) ligands to react with cadmium acetate, a new bulk homochiral 3D metal–organic framework [Cd2(d-cam)2(b4mmp)(DMF)]n (1) has been synthesized. Compound 1 bears an uninodal 6-connected net structure with unprecedent topology, and it has a high thermostability. Moreover, the circular dichroism spectrum and photoluminescent properties for 1 were also investigated.

Full Article

https://link.springer.com/article/10.1007/s10904-019-01328-4

Instrument

J-1500

Keywords

Circular dichroism, Solid state, Stereochemistry, Organic chemistry