Title
Untitled
Author
Lorenzo Arrico, Costanza Benetti, Lorenzo DI Bari
Year
2021
Journal
CHemPhotoChem
Abstract
We report the facile synthesis of TbIII and EuIII adducts able to elicit circularly polarized luminescence. Both the sensitization of the lanthanide-ion-centered luminescence (i. e. the antenna effect) and the chiral environment around the metal ions are brought about by commercially available enantiopure 2,6-bis(oxazolinyl)pyridine ligands (PyBox). This strategy is promising for the development of a wide range of new and simple circularly polarized luminescence (CPL) active LnIII adducts, thanks to the fine tunability of the chemical structure of the PyBox ligands.
Instrument
V-650, J-710, FVS-6000
Keywords
chemical structure, CPL, luminescence