Title
Chiroptical Properties of Nonanuclear Tb(III) Clusters with Chiral Champhor Derivative Ligands
Author
Satoshi Wada, Yuichi Kitagawa, Takayuki Nakanishi, Koji Fushimi, Yasuchika Hasegawa
Year
2015
Journal
e-Journal of Surface Science and Nanotechnology
Abstract
The chiroptical properties of nonanuclear Tb(III) clusters are reported. The nonanuclear Tb(III) clusters are composed of nine Tb(III) ions, ten μ-OH parts, and sixteen chiral organic ligands, (±)-bornyl salicylate. Their chiroptical properties were estimated by circular dichroism (CD) and circularly polarized luminescence (CPL). Their electronic structures were calculated using TD-DFT (B3LYP/6-31G(d)) method.
Instrument
J-1500
Keywords
Circular dichroism, Circularly polarized luminescence, Materials