Title
Dynamic self-assembled polymer: HCl responsive inversion of supramolecular polymer handedness
Author
Arpita Paikar, Debasish Haldar
Year
2017
Journal
RSC Advances
Abstract
A series of discotic tricarboxyamides with varied amino acid side arm functionality and their HCl responsive diverse self-assembly behavior and formation of dynamic polymer is studied. Discotic trisamide 1 obtained from Boc protected L-Lys self-assembled into a long fibrillar aggregate-like supramolecular P helical polymer. However, on addition of HCl, the supramolecular helical handedness of the assemblies is completely inverted. Irrespective of the chiral centres configuration, supramolecular chiral bias is arising from molecular conformations. FE-SEM reveals the formation of right handed entangled polymeric fibers. However, left handed entangled fibers have appeared on addition of 0.12 M HCl. The trisamide 2 containing Boc protected L-Trp exhibits disk like morphology both in the presence and absence of 0.12 M HCl and does not show a change of supramolecular handedness. This demonstrates how remarkably distinct morphologies originate from stimuli responsive building blocks assembled in a subtly different manner.
Instrument
J-815
Keywords
Circular dichroism, Polymers, Chemical stability, Stereochemistry