Title
Efficient and stable sky-blue delayed fluorescence organic light-emitting diodes with CIEy below 0.4
Author
Chin-Yiu Chan, Masaki Tanaka, Hajime Nakanotani, Chihaya Adachi
Year
2018
Journal
Nature Communications
Abstract
Organic light-emitting diodes utilizing thermally activated delayed fluorescence is a potential solution for achieving stable blue devices. Sky-blue devices (CIEy < 0.4) with high stability and high external quantum efficiency (>15%) at 1000 cd m−2 based on either delayed fluorescence or phosphorescence are still limited and very hard to achieve simultaneously. Here, we report the design and synthesis of a new thermally activated delayed fluorescence emitter, 3Ph2CzCzBN. A sky-blue device based on 3Ph2CzCzBN exhibits a high external quantum efficiency of 16.6% at 1000 cd m−2. The device shows a sky-blue electroluminescence of 482 nm and achieves Commission Internationale de l’ Eclairage coordinates of (0.17, 0.36). The sky-blue device exhibits a superb LT90 of 38 h. This is the first demonstration of high-efficiency and stable sky-blue devices (CIEy < 0.4) based on delayed fluorescence, which represents an important advance in the field of blue organic light-emitting diode technology.
Full Article
Instrument
FP-6500
Keywords
Phosphorescence, LEDs, Materials