Title
Hydrogen concentration in plagioclase as a hygrometer of arc basaltic melts: Approaches from melt inclusion analyses and hydrous melting experiments
Author
Morihisa Hamada a, Masashi Ushioda a, Toshitsugu Fujii b, c, Eiichi Takahashi
Year
2013
Journal
Earth and Planetary Science Letters
Abstract
The partition coefficients of hydrogen between plagioclase and basaltic melt were determined by two approaches. For the first part of this study, plagioclase-hosted melt inclusions in mid-ocean ridge basalt (MORB) from the Rodriguez Triple Junction in the Indian Ocean were analyzed. The hydrogen concentration in plagioclase is less than 60 wt ppm water, and the average H2O concentration in melt inclusions is 0.3 wt%. Therefore, the apparent partition coefficient of hydrogen between plagioclase and melt is ≈0.01 on a molar basis. For the second part of this study, hydrous melting experiments of arc basaltic magma were performed at 0.35 GPa using an internally-heated pressure vessel at fO2≈NNO+3. The starting material was hydrous basaltic glass with H2O ranging from 0.8 to 5.5 wt%. A grain of Ca-rich plagioclase (≈1 mg) and 10 mg of powdered basaltic glass were sealed in a Au80Pd20 alloy capsule, and then kept at near the crystallization temperature of plagioclase as a liquidus phase to attain an equilibrium of hydrogen between plagioclase and melt. Combining the results of these two parts of this study, we formulated two linear equations to correlate the hydrogen concentration in plagioclase and the H2O concentration in melt. When H2O in melt is ≤1 wt%,
Instrument
IRT-5000
Keywords
FTIR microscopy, water in nominally anhydrous minerals, hydrogen partitioning, plagioclase, , hydrous melting experimentment, melt inclusion