Title
Memory and Development of Textures of Polydomain Nematic Elastomers
Author
Haruko Higaki, Kenji Urayama, Toshikazu Takigawa
Year
2012
Journal
Macromolecular chemistry and physics
Abstract
The texture development during the polydomain-to-monodomain (PM) transition in nematic elastomers with isotropic (I-PNE) or nematic genesis (N-PNE) is studied. I-PNE exhibits a uniform polydomain texture, and the PM transition occurs at a constant small force, resulting in a uniform monodomain texture. N-PNE exhibits the Schlieren texture that is composed of large domains with many defects and is similar to that before cross-linking. N-PNE requires much more mechanical work than I-PNE for the PM transition. In N-PNE, remnants of the initial texture are still observed in the stretched aligned state, while the initial texture and dimensions are completely restored when the imposed strain is removed. The permanent memory of the initial texture becomes a robust constraint to the rotation of the local directors.
Instrument
IRT-5000
Keywords
FTIR microscopy, Nematic genesis, Nematic elastomers, Memory