Title
Optically Active Poly[2-(sec-butyl)aniline] Nanofibers Prepared via Enantioselective Polymerization
Author
Abdolrahman Shalibor, Ali Reza Modarresi-Alam, Richard B. Kaner
Year
2018
Journal
ACS Omega
Abstract
In this paper, we present a new synthetic route to produce optically active nanofibers of poly[2-(sec-butyl) aniline] (PSBA). Optically active PSBA nanofibers were produced by in situ chemical oxidative polymerization of a racemic monomer, (±)-2-sec-buthylaniline, in the presence of 1.5 M (+)- or (−)-camphor sulfonic acid (HCSA) with a monomer concentration of 0.025 M at 0 °C. The mirror-imaged circular dichroism spectra of both PSBA/(+)HCSA and PSBA/(−)HCSA show that the two polymers are optically active enantiomers, and in this condition, the chemical oxidation of 2SBA is enantioselective polymerization. The produced polymer has a uniform nanofibrillar morphology with an average diameter of 55 nm according to scanning electron microscopy and a number average molecular weight of 4680 g/mol as determined by gel permeation chromatography.
Instrument
J-715
Keywords
Circular dichroism, Stereochemistry, Cotton effect, Chemical stability, Polymers, Nanostructures, Materials