Spontaneous Deracemization of Disc‐like Molecules in the Columnar Phase

September 22, 2019

Title

Spontaneous Deracemization of Disc‐like Molecules in the Columnar Phase

Author

Hiroki Nagayama, Sanjay Kumar Varshney, Masanao Goto, Fumito Araoka, Ken Ishikawa, Veena Prasa and Hideo Takezoe

Year

2009

Journal

Angewandte Chemie

Abstract

Chiral discs: Seemingly flat disc‐like molecules form a columnar phase and spontaneously segregate into macroscopic chiral domains (deracemization). Quantum chemical calculations suggest that these molecules have a twisted axially chiral core (see picture). Their aggregation into chiral superstructures is evidenced by electronic and vibrational circular dichroism spectra.

Instrument

FVS-4000