Title
Syntheses, structures and properties of four inorganic–organic hybrid heteropolymolybdates functionalized by chiral serine ligands
Author
Jiancai Liu, Jing Yu, Qing Han, Bo Shao, Yue Wen, Lijuan Chen, Junwei Zhao
Year
2016
Journal
Inorganic Chemistry Communications
Abstract
Four new inorganic–organic hybrid polyoxomolybdates K2[SeIVMo6O21(L-O2CCHNH3CH2OH)3]·6H2O (1) and K2[SeIVMo6O21(D-O2CCHNH3CH2OH)3]·6H2O (2), K2[TeIVMo6O21(D-O2 CCHNH3CH2OH)3]·6H2O (3) and K2[TeIVMo6O21(L-O2CCHNH3CH2OH)3]·6H2O (4) have been synthesized by a simple one-pot reaction of NaMoO4·2H2O, Na2SeO3/K2TeO3, KCl and corresponding chiral serine ligands in the aqueous medium and further characterized by single-crystal X-ray diffraction, elemental analyses, IR spectra, thermogravimetric (TG) analyses, electrospray ionization mass spectrometry (ESI-MS) and circular dichroism (CD) spectra. 1–4 are the representative chiral heteropolymolybdates featuring that a common {Se/TeMo6} fragment is made up of a six-membered MoO6 octahedral ring functionalized by three serine ligands. TG analyses reveal that 1–4 undergo a two-step weight loss in the temperature range of 25–850 °C.
Instrument
J-815
Keywords
Circular dichroism, Ligand binding, Inorganic chemistry, Materials