Synthesis of D-fructose conjugated ligands via C6 and C1 and their corresponding [Ru(bpy)2(L)]Cl2 complexes

By Michael Pröhl, Pascal D. Moser, Justyna A. Czaplewska, Patrick Hoffmann, Tanja Bus, Anja Traeger, Helmar Görls, Ulrich S. Schubert, Michael Gottschaldt

May 22, 2018

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Title

Synthesis of D-fructose conjugated ligands via C6 and C1 and their corresponding [Ru(bpy)2(L)]Cl2 complexes

Author

Michael Pröhl, Pascal D. Moser, Justyna A. Czaplewska, Patrick Hoffmann, Tanja Bus, Anja Traeger, Helmar Görls, Ulrich S. Schubert, Michael Gottschaldt

Year

2017

Journal

Carbohydrate Research

Abstract

A pyridyl triazole (pyta) modified sucrose ligand was prepared in a seven step synthesis using D-glucose as the protection group for D-fructose and starting from commercially available sucrose. After complexation with Ru(bpy)2Cl2 precursor, the sucrose-conjugated Ru complex of the general formula [Ru(bpy)2(L)]Cl2 was formed. Acidic cleavage of the D-glucose unit led to the first D-fructose conjugated metal complex via D-fructose C6 in literature. Additionally, pyta-modified D-fructose via C1 and the corresponding Ru complex were synthesized. All compounds were analyzed by Rfvalues, specific rotation, NMR, IR, UV/Vis and fluorescence spectroscopy, mass spectrometry and elemental analysis.

Full Article

http://www.sciencedirect.com/science/article/pii/S0008621517301088

Instrument

FP-6500

Keywords

Fluorescence, Inorganic chemistry, Materials