Absolute Reflectance Spectroscopy with UV-Visible and Near Infrared Spectrophotometers

UV-Visible/NIR absolute reflectance spectroscopy can be used to evaluate the spectral properties, film thickness, angular variation or other characteristics of samples such as semiconductors, thin films and optical elements.

The range of absolute reflectance accessories measure  specular reflecting sample (metals, semi conductors, display screens or other materials) while varying the incidence angle (all models). Several models can also be used to measure the transmittance of a sample (without diffuse transmittance). Angular dependent absolute reflectance and transmittance are measured by rotating the sample stage to select an angle of the light incident light to the sample and setting either a synchronous or asynchronous angle for the detector to measure the reflected light or transmitted light.

Diffuse reflectance can also be measured by placing the sample at the rear of the integrating sphere. Diffuse transmittance can be measured by placing the sample at the entrance of the integrating sphere.

Effect of Polarization on Absolute Reflectance

Light from a spectrophotometer that uses a grating is always polarized. The ratio of the intensities of the S and P polarized light is wavelength dependent and is also varies with the characteristics of the grating. Larger incident angles result in a greater difference in the intensity of the S and P polarized light making measurement less accurate. If absolute reflectance is measured at a large angle of incidence, a polarizer should be be set at 45° to minimize the effect of polarization differences.

Overview of the Absolute Reflectance Measurement Models

Manual Measurement

Reflectance Measurement Only – ARV-913, ARN-914/915i

absolute reflectance

Synchronous measurement is made while the incidence and collection angles are maintained at the same angle by rotating the sample stage and detector together. The ARV-913, ARN-914 and ARN-915i can be used to measure the absolute reflectance of a specular reflecting sample or the relative reflectance of a diffusely reflecting sample. Transmittance can be measured with an optional sample mount. An integrating sphere is used with integrated detector(s). The angle of incidence of the sample is set by moving the detector (in the measurement of absolute reflectance). The angular range of the detector is 5°to 90°(angle of incidence). Relative reflectance is measured by placing a sample at the rear of the integrating sphere.

Reflectance and Transmittance Measurement – ARSV-916, ARSN-917/918i

In  asynchronous measurement the incidence and collection angles are set independently. The ARSV-916, ARSN-917 and ARSN-918i  measure the absolute reflectance of a reflective sample or transmittance of a non-diffusing sample. The detector(s) use an integrating sphere and can also measure the relative reflectance or transmittance of samples that diffuse light (the sample holder for relative reflectance is included, the sample holder for transmittance is optional). Absolute reflectance and transmittance are measured by rotating the sample stage to determine the angle of the light incident upon the sample and independently setting the detector angle for the reflected or transmitted light.

Automated Measurement

Reflectance and Transmittance Measurement – ARMV-919, ARMN-920/921i

absolute reflectance spectroscopy

In asynchronous mode the incidence and collection angles are set independently; movement of the sample mount and detector is automated and controlled through the measurement software in the the following models – ARMV-919, ARMN-920 and ARMN-921i. The incidence and collection angles can be set in either synchronous mode, by simultaneously rotating the sample stage and detector,  or in asynchronous mode, the incidence and collection angles can be set independently . Using the built-in linear polarizer the polarization properties of the sample can also be measured using S- or P- polarization.

Absolute Reflectance Optical Layout

Absolute Reflectance

Absolute Reflectance Diagram

Absolute Reflectance Measurement Accessories

SSH-508 Solid Sample Holder

SSH-508 Solid Sample Holder

Used to measure diffuse transmittance of a sample.

Sample Size
Min 30 mm (H) x 30 mm (W) x 0.5 mm (D)
Max 70 mm (H) x 80 mm (W) x 10 mm (D)

ARG-476/GPH-506 Polarizers

ARG-476GPH-506

The ratio of the intensities of the S- and P- polarized light vary according to  wavelength; the greater the angle of incidence of the light on the sample, the greater the difference in intensity of the S and P polarized light, making measurement less accurate. When the angle of incidence is 30° or greater, a polarizer (optional on the manual systems) is recommended for more accurate measurement .

Wavelength Range:250-750 nm(Model ARV-913)

250-2000 nm(Model ARN-914)

250-1600 nm(Model ARN-915i)
Rotation of Plane of Polarization:0°(linearly polarized light in vertical direction) to 90°(linearly polarized light in horizontal direction)

Wide Incident Angle Sample Holder (up to 85º)

6708-H163A for manual type
6708-H460A for automated type

PDU-755 Phase difference measurement unit (Polarizer with measurement software)