Atomistic insights into highly active reconstructed edges of monolayer 2H-WSe2 photocatalyst

March 14, 2022

Title

Atomistic insights into highly active reconstructed edges of monolayer 2H-WSe2 photocatalyst

Author

Mohammad Qorbani, Amr Sabbah, Ying-Ren Lai, Septia Kholimatussadiah, Shaham Quadir, Chih-Yang Huang, Indrajit Shown, Yi-Fan Huang, Michitoshi Hayashi, Kuei-Hsien Chen & Li-Chyong Chen

Year

2022

Journal

Nature Communications

Abstract

Ascertaining the function of in-plane intrinsic defects and edge atoms is necessary for developing efficient low-dimensional photocatalysts. We report the wireless photocatalytic CO2 reduction to CH4 over reconstructed edge atoms of monolayer 2H-WSe2 artificial leaves. Our first-principles calculations demonstrate that reconstructed and imperfect edge configurations enable CO2 binding to form linear and bent molecules. Experimental results show that the solar-to-fuel quantum efficiency is a reciprocal function of the flake size. It also indicates that the consumed electron rate per edge atom is two orders of magnitude larger than the in-plane intrinsic defects. Further, nanoscale redox mapping at the monolayer WSe2–liquid interface confirms that the edge is the most preferred region for charge transfer. Our results pave the way for designing a new class of monolayer transition metal dichalcogenides with reconstructed edges as a non-precious co-catalyst for wired or wireless hydrogen evolution or CO2 reduction reactions.

Instrument

V-670

Keywords

photocatalysts,nanoscale, quantum efficiency