Title
Monitoring electrode/electrolyte interfaces of Li-ion batteries under working conditions: A surface-enhanced Raman spectroscopic study on LiCoO2 composite cathodes
Author
Yuki Takechi-Haraya, Takashi Ohgita, Mana Kotani, Hiroki Kono, Chihiro Saito, Hiroko Tamagaki-Asahina, Kazuchika Nishitsuji, Kenji Marcel Heber, Christian Hess
Year
2022
Journal
SURFACE and INTERFACE ANALYSIS
Abstract
Lithium-ion batteries are commonly used for electrical energy storage in portable devices and are promising systems for large-scale energy storage. However, their application is still limited due to electrode degradation and stability issues. To enhance the fundamental understanding of electrode degradation, we report on the Raman spectroscopic characterization of LiCoO2 cathode materials of working Li-ion batteries. To facilitate the spectroscopic analysis of the solid electrolyte interface (SEI), we apply in situ surface-enhanced Raman spectroscopy under battery working conditions by using Au nanoparticles coated with a thin SiO2 layer (Au@SiO2). We observe a surface-enhanced Raman signal of Li2CO3 at 1090 cm−1 during electrochemical cycling as an intermediate. Its formation/decomposition highlights the role of Li2CO3 as a component of the SEI on LiCoO2 composite cathodes. Our results demonstrate the potential of Raman spectroscopy to monitor electrode/electrolyte interfaces of lithium-ion batteries under working conditions thus allowing relations between electrochemical performance and structural changes to be established.
Instrument
V-770
Keywords
Lithium-ion batteries, energy,