A series of d-glucose-bound optically active π-conjugated polymers (poly-Tr) were synthesized by ternary copolymerization of 2,5-diiodothiophene with diethynyl monomers containing a… Continue reading Chiral Amplification in π-Conjugated Helical Polymers with Circularly Polarized Luminescence
Leah Pandiscia, PhD
May 24, 2018
A Pt(II)phenylbipyridine complex 1, possessing phenylisoxazoles, long alkyl chains, and chiral alkyl chains, was synthesized. Complex 1 formed a stacked assembly in chloroform,… Continue reading A circularly polarized luminescent organogel based on a Pt(II) complex possessing phenylisoxazoles†
Leah Pandiscia, PhD
May 24, 2018
A pair of optically pure triptycene derivatives ((R,R)- and (S,S)-3) containing fluorescent pyrene-based π-conjugated pendant groups attached through amide spacers… Continue reading Chiral Triptycene-Pyrene π-Conjugated Chromophores with Circularly Polarized Luminescence
Leah Pandiscia, PhD
May 24, 2018
The luminescent square-planar Pt(II) complexes of the type [Pt(C^N)(N^N)]+X- have been synthesised, where (C^N) is cyclometallated 2-phenylpyridine ligand, (N^N) a chiral… Continue reading Luminescent water-soluble cycloplatinated complexes: structural, photophysical, electrochemical and chiroptical properties
Leah Pandiscia, PhD
May 24, 2018
A photochromic molecule composed of a helical tetrathiazole framework and two pyrene units bridged by amino acid spacers exhibited on‐off… Continue reading Dynamic Modulation of Circularly Polarized Luminescence in Photoresponsive Assemblies
Leah Pandiscia, PhD
May 24, 2018
A series of d-glucose-bound optically active π-conjugated polymers (poly-Tr) were synthesized by ternary copolymerization of 2,5-diiodothiophene with diethynyl monomers containing a… Continue reading Chiral Amplification in π-Conjugated Helical Polymers with Circularly Polarized Luminescence
Leah Pandiscia, PhD
May 24, 2018
Novel tetraphenylethylene (TPE) triangular macrocycle crown ethers bearing three ether crown rings were synthesized by connecting three TPE crown ether… Continue reading Chiroptical Property of TPE Triangular Macrocycle Crown Ethers from Propeller-Like Chirality Induced by Chiral Acids
Leah Pandiscia, PhD
May 24, 2018
A Pt(II)phenylbipyridine complex 1, possessing phenylisoxazoles, long alkyl chains, and chiral alkyl chains, was synthesized. Complex 1 formed a stacked assembly in chloroform,… Continue reading A circularly polarized luminescent organogel based on a Pt(II) complex possessing phenylisoxazoles†
Leah Pandiscia, PhD
May 24, 2018
A liquid crystal host–guest system composed of achiral organic molecules (host) and colored chiral metal complexes (guest) was fabricated to… Continue reading Left- and right-circularly polarized light-sensing based on colored and mechano-responsive chiral nematic liquid crystals
Leah Pandiscia, PhD
May 24, 2018
Leah Pandiscia, PhD
May 24, 2018
Herein, a pair of enantiomers, (S)-PPPtriAm and (R)-PPPtriAm, with three chiral substituents and their raceme rac-PPPtriAm derived from conjugated luminogen pentaphenylpyrrole… Continue reading Aggregation-induced emission enhancement and aggregation-induced circular dichroism of chiral pentaphenylpyrrole derivatives and their helical self-assembly
Leah Pandiscia, PhD
May 24, 2018
Enantiomeric glutamate gelators containing a spiropyran moiety are designed and found to self-assemble into a nanohelix through gelation. Upon alternating… Continue reading Reversible Quadruple Switching with Optical, Chiroptical, Helicity, and Macropattern in Self-Assembled Spiropyran Gels
Leah Pandiscia, PhD
May 24, 2018
Herein, two pairs of chiral 1,8-naphthalimide-based enantiomers incorporating D/L-alanine and pyrene fluorophore moieties were designed and synthesized. The fluorescence emission gradually… Continue reading Circularly polarized luminescence of chiral 1,8-naphthalimide-based pyrene fluorophore induced via supramolecular self-assembly
Leah Pandiscia, PhD
May 24, 2018
Circularly polarized light (CPL), regarded as a true chiral entity, has been suggested as one possible origin of the homochirality… Continue reading Chiral induction, transfer and modulation in C3-symmetric Columnar Liquid Crystalline Assemblies
Leah Pandiscia, PhD
May 24, 2018
Multiple pyrenes as pendants of enantioimpure di‐/tripeptides (abbreviated as N‐LD‐C, N‐DL‐C, N‐LLD‐C and N‐DDL‐C) showed pyrene‐origin CPL and CD signals,… Continue reading Circularly polarised luminescence of pyrenyl di- and tri-peptides with mixed D- and L-amino acid residues
Leah Pandiscia, PhD
May 24, 2018
Circularly polarized luminescent (CPL) materials are currently attracting great interest. While a chiral building is usually necessary in order to… Continue reading Full-Color Tunable Circularly Polarized Luminescent Nanoassemblies of Achiral AIEgens in Confined Chiral Nanotubes
Leah Pandiscia, PhD
May 24, 2018
Complexes of Eu(III)(hfa)3 with a C2-symmetric planar P(III) ligand exhibited intense circularly polarised luminescence (CPL) due to 5D0→7F1 and 5D0→7F2 transitions, with the signs and shapes… Continue reading Complexes of Eu(III)(hfa)3 with a planar chiral P(III) ligand (Phanephos): solvent-sensitive sign inversion of circularly polarised luminescence
Leah Pandiscia, PhD
May 24, 2018
The luminescent square-planar Pt(II) complexes of the type [Pt(C^N)(N^N)]+X- have been synthesised, where (C^N) is cyclometallated 2-phenylpyridine ligand, (N^N) a chiral… Continue reading Luminescent water-soluble cycloplatinated complexes: structural, photophysical, electrochemical and chiroptical properties
Leah Pandiscia, PhD
May 24, 2018
To the best of our knowledge this is the first report on the application of induced circularly polarized luminescence (CPL)… Continue reading Induced Circularly Polarized Luminescence for Revealing DNA Binding with Fluorescent Dyes
Leah Pandiscia, PhD
May 24, 2018
Three kinds of chiral BINOL-based polymers could be synthesized by polymerization in a Pd-catalyzed cross-coupling reaction. The resulting chiral polymers… Continue reading Circularly polarized luminescence based chirality transfer of the chiral BINOL moiety viarigid π-conjugation chain backbone structures
Leah Pandiscia, PhD
May 24, 2018