Two new ent-3,4-seco-labdane diterpenoids from Callicarpa nudiflora

July 28, 2017

Title

Two new ent-3,4-seco-labdane diterpenoids from Callicarpa nudiflora

Author

Lin Dong, Xiao-Po Zhang, Ming-Sheng Liu, Yan-Mei Li, Jin-Hui Wang, Yi Wang

Year

2012

Journal

Journal of Asian Natural Products Research

Abstract

Two new ent-3,4-seco-labdane diterpenoids, methylcallicarpate (1) and callicarpic acid (2), were isolated from the leaves of Callicarpa nudiflora Hook et Arn. Their structures and relative configurations were established by analysis of spectroscopic data. Their absolute configurations were assigned by the application of the CD technique for the first time among the ent-3,4-seco-labdane-type diterpenes.

Instrument

J-815

Keywords

Circular dichroism, Absolute configuration, Natural products